Can i applied it directly to the new wood surface

Yes you can apply directly on the wood surface.

How much would be needed for 6 dining chairs?

That depends upon the total wood surface area of your Chairs, probably 250 ml Will be sufficient for your purpose ,if you do carefully not wasting the stain by excess qty

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Specifications

Colour	DARK WALNUT
Brand	Varathane
Surface Recommendation	Wood
Material	Wood
Model Name	Varathane Premium Fast Dry Furniture Wood Stain (Dark Walnut Color)
Size	(Half Pint/236ml)
Coating Description	Water-based, fast-drying wood stain with nano pigments for enhanced color clarity, suitable for wood surfaces.
Item dimensions L x W x H	8 x 14 x 21 Centimeters
Item Weight	250 Grams
Finish Type	Flat
Liquid Volume	236 Millilitres
Package Information	Tin
Number of Items	1
Manufacturer	Rust-Oleum, Rust-Oleum
Net Quantity	237 millilitre
Global Trade Identification Number	00020066211653
UPC	020066211653
Manufacturer	Rust-Oleum
Country of Origin	USA
Item model number	262025
Product Dimensions	8 x 14 x 21 cm; 250 g
ASIN	B011VTB4X0

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